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Preparation of high performance dual network PAM/P123 gel electrolyte and application in rechargeable Zn-MnO2 batteries
- Source :
- Cailiao gongcheng, Vol 51, Iss 1, Pp 130-139 (2023)
- Publication Year :
- 2023
- Publisher :
- Journal of Materials Engineering, 2023.
-
Abstract
- Flexible energy storage devices are at the forefront of next-generation power supplies, one of the most important components of which is the gel electrolyte. The dual network gel electrolyte for PAM/P123 zinc ion batteries was prepared by free radical polymerization. It was found that the addition of a small amount of triblock copolymer P123 can macroscopically improve the tensile strength, toughness and compressive strength of the gel electrolyte. Microscopically, the gel skeleton forms 0.6 μm mesopores and increases the surface pore distribution density, thereby improving the wettability of the electrolyte. The PAM/P123 series electrolytes not only have a high average swelling rate, but also have a higher conductivity than pure PAM electrolyte in the range of -30℃ to 65℃. Among which, PAM/P123-2 is a series of electrolytes with the best performance, with an average swelling rate of 1920.79%, and the conductivity at 0℃ is 36.2 mS·cm-1.The Zn/MnO2 battery prepared by using PAM/P123-2 gel electrolyte is stable during cycling at 0℃, with the capacity retention rate reaching 82.39% after 1000 cycles.
Details
- Language :
- Chinese
- ISSN :
- 10014381
- Volume :
- 51
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Cailiao gongcheng
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.4538e1e50602477e873c3b68d00b5f6a
- Document Type :
- article
- Full Text :
- https://doi.org/10.11868/j.issn.1001-4381.2021.000198