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Synthesis, NMR, DFT and antimicrobial studies of Zn(II) complexes with N-benzyloxycarbonyl-S-alanine
- Source :
- Journal of the Serbian Chemical Society, Vol 73, Iss 8-9, Pp 815-824 (2008)
- Publication Year :
- 2008
- Publisher :
- Serbian Chemical Society, 2008.
-
Abstract
- In this study, the first complexes of Zn(II) with the N-benzyloxycar- bonyl-S-alaninato ligand (N-Boc-S-ala) were synthesized. The new complexes were characterized by elemental analysis, conductometric measurements, IR, 1H-NMR, 13C-NMR and 2D-NMR spectroscopy. On the basis of the experimental data, tetrahedral geometry of the Zn(II) complexes was proposed. A very good agreement between the NMR and DFT calculated data was obtained. Investigation of antimicrobial activity of the newly synthesized complexes was also performed. It was established that [Zn(N-Boc-S-ala)2] was selective and acts only on Candida albicans.
Details
- Language :
- English
- ISSN :
- 03525139 and 18207421
- Volume :
- 73
- Issue :
- 8-9
- Database :
- Directory of Open Access Journals
- Journal :
- Journal of the Serbian Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.46cfb500ea644e0f8e781157badae727
- Document Type :
- article
- Full Text :
- https://doi.org/10.2298/JSC0809815M