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Poly[μ3-β-alanine-aqua-μ4-sulfato-dilithium]

Authors :
M. Daniel Sweetlin
Shibu M. Eapen
S. Perumal
S. Ramalingom
Source :
Acta Crystallographica Section E, Vol 68, Iss 2, Pp m206-m207 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

The title compound, [Li2(SO4)(C3H7NO2)(H2O)]n, is a coordination polymer in which the β-alanine residues remain in the zwitterionic form. The crystal structure consists of corrugated sheets of [LiO4] and [SO4] tetrahedra parallel to (010) with the β-alanine molecules located between the sheets. The two independent Li+ cations are four-coordinated by O atoms in a distorted tetrahedral geometry. The crystal structure is formed by stacking of alternate organic and inorganic layers along the a axis. The crystal structure is further stabilized by N—H...O hydrogen bonds.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
2
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.48f1561b017e4e7897e647f19e774c7b
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812002115