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Bis(N′-benzoylpyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate

Authors :
Xiu-Qing Zhang
Chun-Ying Li
He-Dong Bian
Qing Yu
Hong Liang
Source :
Acta Crystallographica Section E, Vol 66, Iss 11, Pp m1360-m1360 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the title complex, [Cu(C13H11N3O2)2(C12H8N2)](NO3)2, the CuII atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the CuIIatom by a pyridine N atom. These four atoms form a slightly distorted square-planar N4 donor set. In the packing, two additional Cu...O interactions occur [Cu...O = 2.462 (2) Å], resulting in a typical Jahn–Teller-distorted octahedral environment around the Cu atom. N—H...O hydrogen bonds result in a three-dimensional network. The O atoms of the anion are disordered over two positions in a 0.68 (2):0.32 (2) ratio.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
11
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.4ac3e0c1d4374a220ac7c879464fd
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810038985