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Ethyl (2Z)-3-oxo-2-(3,4,5-trimethoxybenzylidene)butanoate

Authors :
Julio Zukerman-Schpector
Camila Lury Hino
Paulo J. S. Moran
Bruno R. S. de Paula
Seik Weng Ng
Edward R. T. Tiekink
Source :
Acta Crystallographica Section E, Vol 69, Iss 9, Pp o1474-o1474 (2013)
Publication Year :
2013
Publisher :
International Union of Crystallography, 2013.

Abstract

In the title compound, C16H20O6, the conformation about the C=C double bond [1.344 (2) Å] is Z. With respect to this bond, the ketone is almost coplanar [C—C—C—O torsion angle = −179.60 (10)°] and the ester is almost perpendicular [C—C—C—O = 78.42 (13)°]. The methoxy substituents of the central benzene ring are either almost coplanar [C—C—O—C = 3.54 (15) and 177.70 (9)°] or perpendicular [C—C—O—C = 80.08 12)° for the central substituent]. In the crystal, the three-dimensional architecture features C—H...O and π–π [inter-centroid distance = 3.6283 (6) Å] interactions.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
69
Issue :
9
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.4bf452b3a3b04a51928ceb632571ee1d
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536813023374