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Ethyl (2Z)-3-oxo-2-(3,4,5-trimethoxybenzylidene)butanoate
- Source :
- Acta Crystallographica Section E, Vol 69, Iss 9, Pp o1474-o1474 (2013)
- Publication Year :
- 2013
- Publisher :
- International Union of Crystallography, 2013.
-
Abstract
- In the title compound, C16H20O6, the conformation about the C=C double bond [1.344 (2) Å] is Z. With respect to this bond, the ketone is almost coplanar [C—C—C—O torsion angle = −179.60 (10)°] and the ester is almost perpendicular [C—C—C—O = 78.42 (13)°]. The methoxy substituents of the central benzene ring are either almost coplanar [C—C—O—C = 3.54 (15) and 177.70 (9)°] or perpendicular [C—C—O—C = 80.08 12)° for the central substituent]. In the crystal, the three-dimensional architecture features C—H...O and π–π [inter-centroid distance = 3.6283 (6) Å] interactions.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 69
- Issue :
- 9
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.4bf452b3a3b04a51928ceb632571ee1d
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536813023374