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Octakis(2-chlorobenzyl)di-μ2-hydroxido-di-μ3-oxido-bis(2-phenylacetato)tetratin(IV)
- Source :
- Acta Crystallographica Section E, Vol 66, Iss 5, Pp m535-m536 (2010)
- Publication Year :
- 2010
- Publisher :
- International Union of Crystallography, 2010.
-
Abstract
- The asymmetric unit of the title compound, [Sn4(C7H6Cl)8(C8H7O2)2O2(OH)2], comprises one-half of the centrosymmetric tin(IV) complex. μ3-Oxide and μ2-hydroxide bridges link the four five-coordinate SnIV atoms to generate three fused four-membered Sn—O—Sn—O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two μ3-oxide anions and a μ2-hydroxide ligand, together with two 2-chlorobenzyl groups. The exocyclic Sn atoms each carry a monodentate phenylacetate ligand, two 2-chlorobenzyl groups, and μ3-oxide and μ2-hydroxide ligands. Both types of Sn atoms adopt a distorted trigonal–bipyramidal coordination geometry. The molecular conformation is stabilized by intramolecular O—H...O interactions involving the μ2-hydroxide ligands and the C=O group of the phenylacetate ligand.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 66
- Issue :
- 5
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.4eca537583489bbe6df0ef5413ac6f
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536810012559