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Synthesis and Evaluation of FeSX/TiO2 for the Photocatalytic Degradation of Phenol under Visible-Light Region

Authors :
Diego Alvarez-Bustos
Felipe Sanchez-Minero
Victor Santes
Issis Claudette Romero-Ibarra
José Antonio de los Reyes Heredia
Reyna Rios-Escobedo
Francisco Tzompantzi-Morales
Carlos Eduardo Santolalla-Vargas
Source :
Catalysts, Vol 12, Iss 5, p 457 (2022)
Publication Year :
2022
Publisher :
MDPI AG, 2022.

Abstract

In the present work, phenol was used as a model molecule to the photocatalytic evaluation of TiO2 impregnated with iron sulphide and chlorine on a visible-light reactor. The iron–chlorine catalyst was prepared by incipient impregnation with the metal precursors, Fe (NO3)3 and NaCl on previously calcined TiO2. The catalyst was sulphurized with H2S at 300 °C for 1 h. The catalysts were prepared at different chlorine concentrations using HYDRA chemical equilibrium diagrams to obtain different fractions of FeCl+. The oxide catalysts were characterized with diffuse reflectance (DRS UV–Vis) and temperature programmed reduction analysis (TPR). Sulphurized catalysts were characterized with Raman spectrometry and X-ray photoelectron spectrometry (XPS). The FeS–2Cl/TiO2 catalyst presented 8.35 times higher photodegradation than TiO2 and 6.4 times higher compared to the FeS–0.25Cl/TiO2 catalyst. DRS and XPS showed similar results of band gap, proving that the catalyst remain stable after sulphurisation. The TPR results of FeS–2Cl/TiO2 showed an increment of 86.29% in Fe2+/Fe3+ compared to FeS–0.25Cl/TiO2. XPS and Raman results for oxide and sulphated iron species relation suggested that FeS–2Cl/TiO2 decreased 4.45% compared to FeS–0.25Cl/TiO2 catalyst. XPS semiquantitative for S/Fe results showed that the FeS–2Cl/TiO2 catalyst increased 73.17% in comparison to FeS–0.25Cl/TiO2. These results suggested the increment of sulphurisation degree for FeS–2Cl/TiO2. In this regard, the catalyst characterization results showed that the presence of FeCl+ (0.85 fractions) in solution before impregnation promoted the active sulphide species maintaining the band gap and improved the degradation of phenol on visible light.

Details

Language :
English
ISSN :
20734344
Volume :
12
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Catalysts
Publication Type :
Academic Journal
Accession number :
edsdoj.52e53a77fd643d1bbf509070c27172d
Document Type :
article
Full Text :
https://doi.org/10.3390/catal12050457