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Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity
- Source :
- Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
- Publication Year :
- 2020
- Publisher :
- Nature Portfolio, 2020.
-
Abstract
- C-C bond scission of unstrained cycloketones with high regioselectivity is a challenging synthetic task. Here, the authors show a facile C-C cleavage of cyclohexanones and cyclopentanones with unusual selectivity under mild conditions with the aid of an in situ formed side-chain aryl radical.
- Subjects :
- Science
Subjects
Details
- Language :
- English
- ISSN :
- 20411723
- Volume :
- 11
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Nature Communications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.55051764b1994bef9084f3bc8a817022
- Document Type :
- article
- Full Text :
- https://doi.org/10.1038/s41467-020-14435-5