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Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size

Authors :
Kruppa Sebastian Volker
Bäppler Florian
Holzer Christof
Dietrich Fabian
Diller Rolf
Klopper Wim
Riehn Christoph
Source :
EPJ Web of Conferences, Vol 205, p 09019 (2019)
Publication Year :
2019
Publisher :
EDP Sciences, 2019.

Abstract

Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.

Subjects

Subjects :
Physics
QC1-999

Details

Language :
English
ISSN :
2100014X
Volume :
205
Database :
Directory of Open Access Journals
Journal :
EPJ Web of Conferences
Publication Type :
Academic Journal
Accession number :
edsdoj.56e61c387e4a008f6310d53bd19148
Document Type :
article
Full Text :
https://doi.org/10.1051/epjconf/201920509019