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Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer

Authors :
Alessandro Strada
Mattia Fredditori
Giuseppe Zanoni
Stefano Protti
Source :
Molecules, Vol 24, Iss 7, p 1318 (2019)
Publication Year :
2019
Publisher :
MDPI AG, 2019.

Abstract

The behavior of 2-naphthol and 7-bromo-2-naphthol as organic photoacids are exploited in organic synthesis for the preparation of benzyl sulfides (using a trichloroacetimidate derivative as the starting substrate) and polycyclic amines via acid catalyzed condensation of 1,2,3,4-tetrahydroisoquinoline with aldehydes.

Subjects

Subjects :
excited state proton transfer
acid catalyzed synthesis
photocatalysis
tris(bipyridine)ruthenium(II) chloride
Organic chemistry
QD241-441

Details

Language :
English
ISSN :
14203049
Volume :
24
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Molecules
Publication Type :
Academic Journal
Accession number :
edsdoj.5d08bc3a405a4b78b1d9cc212dcf588e
Document Type :
article
Full Text :
https://doi.org/10.3390/molecules24071318
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