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[1-(2,5-Dichloroanilino)-5-methyl-1H-1,2,3-triazol-4-yl]methanol
- Source :
- IUCrData, Vol 1, Iss 1, p x152447 (2016)
- Publication Year :
- 2016
- Publisher :
- International Union of Crystallography, 2016.
-
Abstract
- In the title compound, C10H10Cl2N4O, the hydroxy group and benzene ring are disposed to opposite sides of the central 1,2,3-triazolyl ring. The dihedral angle between the five- and six-membered rings is 87.51 (12)°, and the C—O bond of the hydroxy group lies almost normal to the plane of the 5-membered ring [N—C—C—O = −93.2 (2)°]. An intramolecular amino-N—H...Cl hydrogen bond is noted. In the extended structure, supramolecular layers in the ab plane are formed via hydroxy-O—H...N(ring) and amine-N—H...O(hydroxy) hydrogen bonds. The layers are connected along the c axis by π–π contacts between benzene rings [inter-centroid distance = 3.7789 (13) Å] and by C—Cl...π interactions.
- Subjects :
- crystal structure
1,2,3-triazolyl
alcohol
hydrogen bonding
Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 24143146
- Volume :
- 1
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- IUCrData
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.5eb77558da4428d9b7b975fabed1d7e
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2414314615024475