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[1-(2,5-Dichloroanilino)-5-methyl-1H-1,2,3-triazol-4-yl]methanol

Authors :
Anna C. Cunha
Alessandro K. Jordão
Maria C. B. V. de Souza
Vitor F. Ferreira
Maria C. B. de Almeida
James L. Wardell
Edward R. T. Tiekink
Source :
IUCrData, Vol 1, Iss 1, p x152447 (2016)
Publication Year :
2016
Publisher :
International Union of Crystallography, 2016.

Abstract

In the title compound, C10H10Cl2N4O, the hydroxy group and benzene ring are disposed to opposite sides of the central 1,2,3-triazolyl ring. The dihedral angle between the five- and six-membered rings is 87.51 (12)°, and the C—O bond of the hydroxy group lies almost normal to the plane of the 5-membered ring [N—C—C—O = −93.2 (2)°]. An intramolecular amino-N—H...Cl hydrogen bond is noted. In the extended structure, supramolecular layers in the ab plane are formed via hydroxy-O—H...N(ring) and amine-N—H...O(hydroxy) hydrogen bonds. The layers are connected along the c axis by π–π contacts between benzene rings [inter-centroid distance = 3.7789 (13) Å] and by C—Cl...π interactions.

Details

Language :
English
ISSN :
24143146
Volume :
1
Issue :
1
Database :
Directory of Open Access Journals
Journal :
IUCrData
Publication Type :
Academic Journal
Accession number :
edsdoj.5eb77558da4428d9b7b975fabed1d7e
Document Type :
article
Full Text :
https://doi.org/10.1107/S2414314615024475