Investigation of the effect of relative humidity on micro lime consolidation of degraded earthen structures

Abstract Micro lime, hydrated lime (Ca (OH)2) with particle sizes of 1-3μ dispersed in isopropanol, can be used to reinforce deteriorated earthen structures. The consolidation effect depends on the amount of moisture present in the structure or in the ambient air. This study investigates the influence of different levels of relative humidity (RH) on the consolidation effect of micro lime on earthen structures, the chemical processes responsible for the consolidation and the physical changes to the structure. The aim is to gain a deeper understanding of the underlying chemical reactions and to identify a potential limit to the applicability of this consolidation method in low RH environments. The fact that many of these sites are located in arid climates greatly influences the practical application of micro lime in the conservation of historical earthen structures. To characterize the consolidation effect of micro lime, unconfined compressive strength and exposure to wet and dry cycles were used. The properties of the reaction products and the bonding between soil particles and micro lime were investigated using thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). At RH levels of 25%, 45%, 65% and 90%, the unconfined compressive strength (UCS) and the modulus of deformation at 50% strength (E50) of the micro lime-reinforced specimens demonstrated an increase with humidity. This led to a significant improvement in their ability to resist the effects of dry–wet cycles. Results from thermal gravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) indicate that micro lime interacts with the soil matrix via carbonation, with the reaction rate increasing with humidity. At 25% RH, vaterite was produced and residual free lime was observed, whereas at humidity levels of 45% and above, the reaction yielded vaterite and aragonite. The lime treatment did not significantly alter the pore structure of the soil specimens. The total porosity of the specimens was only slightly reduced, with the main effect of the lime treatment being a reduction in the number of large pores.