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Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products
- Source :
- Molecules, Vol 10, Iss 1, Pp 190-194 (2005)
- Publication Year :
- 2005
- Publisher :
- MDPI AG, 2005.
-
Abstract
- An easy and safe, though only moderately effective method is presented forpreparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using thecommercially available and easily handled urea-hydrogen peroxide adduct (UHP) as theoxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst)mixtures, at 40 oC for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fullyinterpreted 1H- and 13C-NMR spectra of the ArI(OAc)2 products are reported.
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 10
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Molecules
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.62f321d620544f0384e97f568b2d7c11
- Document Type :
- article
- Full Text :
- https://doi.org/10.3390/10010190