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Easy and Safe Preparations of (Diacetoxyiodo) arenes from Iodoarenes, with Urea-Hydrogen Peroxide Adduct (UHP) as the Oxidant and the Fully Interpreted 1H- and 13C-NMR Spectra of the Products

Authors :
Lech Skulski
Agnieszka Zielinska
Source :
Molecules, Vol 10, Iss 1, Pp 190-194 (2005)
Publication Year :
2005
Publisher :
MDPI AG, 2005.

Abstract

An easy and safe, though only moderately effective method is presented forpreparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using thecommercially available and easily handled urea-hydrogen peroxide adduct (UHP) as theoxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst)mixtures, at 40 oC for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fullyinterpreted 1H- and 13C-NMR spectra of the ArI(OAc)2 products are reported.

Details

Language :
English
ISSN :
14203049
Volume :
10
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Molecules
Publication Type :
Academic Journal
Accession number :
edsdoj.62f321d620544f0384e97f568b2d7c11
Document Type :
article
Full Text :
https://doi.org/10.3390/10010190