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5,5′-(p-Phenylene)di-1H-tetrazole
- Source :
- Acta Crystallographica Section E, Vol 64, Iss 1, Pp o40-o40 (2008)
- Publication Year :
- 2008
- Publisher :
- International Union of Crystallography, 2008.
-
Abstract
- Crystals of the title organic compound, C8H6N8, were generated in situ through the [2 + 3]-cycloaddition reaction involving the precursor 1,4-dicyanobenzene and azide in water with Zn2+ as Lewis acid. The asymmetric unit consists of one half-molecule, and a twofold axis of symmetry passes through the centre of the benzene ring. There is an intermolecular N—H...N hydrogen bond. The molecules are assembled into a three-dimensional supramolecular framework by π–π stacking interactions, with a perpendicular distance of 3.256 Å [centroid–centroid = 3.9731 (8) Å] between two tetrazole ring planes, and 3.382 Å between the benzene ring and tetrazole ring planes [centroid–centroid = 3.5010 (9) Å].
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 64
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.637c0d8fa149b78cc58971b50f28e9
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536807062538