Back to Search
Start Over
Coupling the vanadium-induced amorphous/crystalline NiFe2O4 with phosphide heterojunction toward active oxygen evolution reaction catalysts
- Source :
- Nanotechnology Reviews, Vol 11, Iss 1, Pp 3165-3173 (2022)
- Publication Year :
- 2022
- Publisher :
- De Gruyter, 2022.
-
Abstract
- Developing efficient and robust electrocatalysts is increasingly essential for water splitting, severely hindered by the sluggish four-electron transfer process of oxygen evolution reaction (OER). Amorphous/crystalline heterophase engineering has recently emerged as a promising electronic modulation approach for OER catalysts but suffers from poor conductivity of the amorphous structure. Here, we coupled the amorphous/crystalline NiFe2O4 induced by vanadium doping with NiP heterojunction, highlighting the synergistic effect in modulating the electronic structures and the complementary effect in promoting conductivity. As a superior electrocatalyst to commercial RuO2, the as-prepared NFO-V0.3-P showed a low overpotential of 277 mV at the current density of 20 mA cm−2, a Tafel slope of 45 mV dec−1, and long-term stability. The excellent OER catalytic activity is attributed to the synergistic effect at the heterophase interface with rich active sites, fine-tuning of electronic regulation, and enhanced conductivity.
Details
- Language :
- English
- ISSN :
- 21919097
- Volume :
- 11
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Nanotechnology Reviews
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.63871eff7c714d3f9349d5d659913d5b
- Document Type :
- article
- Full Text :
- https://doi.org/10.1515/ntrev-2022-0450