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Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ2N3,O4)copper(II) N,N-dimethylformamide disolvate
- Source :
- Acta Crystallographica Section E, Vol 66, Iss 8, Pp m896-m896 (2010)
- Publication Year :
- 2010
- Publisher :
- International Union of Crystallography, 2010.
-
Abstract
- In the title complex, [Cu(C8H9N2O4)2(H2O)2]·2C3H7NO, the CuII ion, lying on an inversion center, is six-coordinated in a slightly distorted octahedral geometry. Two N atoms and two O atoms from two H2pimda (H3pimda is 2-propyl-1H-4,5-dicarboxylic acid) ligands are in the equatorial plane. The axial positions are occupied by two O atoms from two water molecules. A two-dimensional supramolecular network parallel to (001) is constructed by N—H...O and O—H...O hydrogen bonds. An intramolecular O—H...O hydrogen bond is also observed.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 66
- Issue :
- 8
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.63be81df97234142bc70b4ffcc9e6a5c
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536810025249