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Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ2N3,O4)copper(II) N,N-dimethylformamide disolvate

Authors :
Lan-Zhen He
Shi-Jie Li
Wen-Dong Song
Dong-Liang Miao
Source :
Acta Crystallographica Section E, Vol 66, Iss 8, Pp m896-m896 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the title complex, [Cu(C8H9N2O4)2(H2O)2]·2C3H7NO, the CuII ion, lying on an inversion center, is six-coordinated in a slightly distorted octahedral geometry. Two N atoms and two O atoms from two H2pimda (H3pimda is 2-propyl-1H-4,5-dicarboxylic acid) ligands are in the equatorial plane. The axial positions are occupied by two O atoms from two water molecules. A two-dimensional supramolecular network parallel to (001) is constructed by N—H...O and O—H...O hydrogen bonds. An intramolecular O—H...O hydrogen bond is also observed.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.63be81df97234142bc70b4ffcc9e6a5c
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810025249