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Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB4

Authors :
Xiaoni Zhang
Miwa Hikichi
Takushi Iimori
Yuki Tsujikawa
Mei Yuan
Masafumi Horio
Kunio Yubuta
Fumio Komori
Masahiro Miyauchi
Takahiro Kondo
Iwao Matsuda
Source :
Molecules, Vol 28, Iss 7, p 2985 (2023)
Publication Year :
2023
Publisher :
MDPI AG, 2023.

Abstract

We present an enhanced method for synthesizing sheets of borophane. Despite the challenges associated with low efficiency, we discovered that incorporating hydrochloric acid into the ion-exchange reaction significantly improved the production yield from 20% to over 50%. After a thorough examination of the reaction, we gained insight into the underlying mechanisms and found that the use of hydrochloric acid provides two key benefits: accelerated production of borophene and isolation of high-purity products. This method has the potential to pave the way for the production of novel topological 2D materials with potential industrial applications.

Details

Language :
English
ISSN :
14203049
Volume :
28
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Molecules
Publication Type :
Academic Journal
Accession number :
edsdoj.64ba73dab84d66a727b0c2d01a1201
Document Type :
article
Full Text :
https://doi.org/10.3390/molecules28072985