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1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (Rp)-2-(diphenylphosphino)ferrocene-1-carboxylate

Authors :
Petr Štěpnička
Martin Lamač
Ivana Císařová
Source :
Acta Crystallographica Section E, Vol 65, Iss 10, Pp m1252-m1253 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

The title compound, [Fe(C5H5)(C30H32O7P)], which is an intermediate in the synthesis of (Rp)-2-(diphenylphosphino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P212121. In general, the molecular geometry is very similar to that of the corresponding 2,1′-bis(diphenylphosphino) congener. The ferrocene unit assumes a regular geometry with the proximal bulky substituents efficiently avoiding mutual spatial contacts. In the crystal, the molecules participate in weak intra- and intermolecular C—H...O interactions.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
10
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.6785b64df5bf408ca290205602350c6c
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809038653