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1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (Rp)-2-(diphenylphosphino)ferrocene-1-carboxylate
- Source :
- Acta Crystallographica Section E, Vol 65, Iss 10, Pp m1252-m1253 (2009)
- Publication Year :
- 2009
- Publisher :
- International Union of Crystallography, 2009.
-
Abstract
- The title compound, [Fe(C5H5)(C30H32O7P)], which is an intermediate in the synthesis of (Rp)-2-(diphenylphosphino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P212121. In general, the molecular geometry is very similar to that of the corresponding 2,1′-bis(diphenylphosphino) congener. The ferrocene unit assumes a regular geometry with the proximal bulky substituents efficiently avoiding mutual spatial contacts. In the crystal, the molecules participate in weak intra- and intermolecular C—H...O interactions.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 65
- Issue :
- 10
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.6785b64df5bf408ca290205602350c6c
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536809038653