Back to Search Start Over

Reactive collisions in confined geometries

Authors :
Zbigniew Idziaszek
Krzysztof Jachymski
Paul S Julienne
Source :
New Journal of Physics, Vol 17, Iss 3, p 035007 (2015)
Publication Year :
2015
Publisher :
IOP Publishing, 2015.

Abstract

We consider low energy threshold reactive collisions of particles interacting via a van der Waals potential at long range in the presence of external confinement and give analytic formulas for the confinement modified scattering in such circumstances. The reaction process is described in terms of the short range reaction probability. Quantum defect theory is used to express elastic and inelastic or reaction collision rates analytically in terms of two dimensionless parameters representing phase and reactivity. We discuss the modifications to Wigner threshold laws for quasi-one-dimensional and quasi-two-dimensional geometries. Confinement-induced resonances are suppressed due to reactions and are completely absent in the universal limit where the short-range loss probability approaches unity.

Details

Language :
English
ISSN :
13672630
Volume :
17
Issue :
3
Database :
Directory of Open Access Journals
Journal :
New Journal of Physics
Publication Type :
Academic Journal
Accession number :
edsdoj.7182cfe4257c4b1b8dc62ebd8921ea44
Document Type :
article
Full Text :
https://doi.org/10.1088/1367-2630/17/3/035007