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2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene

Authors :
Hai-Kun Luo
Rui-Rui Qin
Ming-Yang He
Source :
Acta Crystallographica Section E, Vol 70, Iss 6, Pp o698-o698 (2014)
Publication Year :
2014
Publisher :
International Union of Crystallography, 2014.

Abstract

The title compound, C20H16F4N2S2, is a flexible bisthiophene-type Schiff base ligand with a perfluorinated backbone. The terminal thiophene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetrafluorinated benzene ring with dihedral angles of 61.2 (2) and 77.7 (1)°. In the crystal, there are π–π interactions involving the benzene ring and the thiophene ring of a symmetry-related molecule with a centroid–centroid separation of 3.699 (3) Å.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
70
Issue :
6
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.72994f2b284100acd9eefe5f329de4
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536814011398