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Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

Authors :
Andreas Kirschning
Andreas Schönberger
Nuria Merayo
Georgia Sourkouni-Argirusi
Silvie Domann
Source :
Molecules, Vol 6, Iss 1, Pp 61-66 (2001)
Publication Year :
2001
Publisher :
MDPI AG, 2001.

Abstract

Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH− -form) vinyl silanes are converted into epoxysilanes.

Details

Language :
English
ISSN :
14203049
Volume :
6
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Molecules
Publication Type :
Academic Journal
Accession number :
edsdoj.7d3cad7a604043db9b72927d17c91880
Document Type :
article
Full Text :
https://doi.org/10.3390/60100061