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Graphite as a Long‐Life Ca2+‐Intercalation Anode and its Implementation for Rocking‐Chair Type Calcium‐Ion Batteries
- Source :
- Advanced Science, Vol 6, Iss 24, Pp n/a-n/a (2019)
- Publication Year :
- 2019
- Publisher :
- Wiley, 2019.
-
Abstract
- Abstract Herein, graphite is proposed as a reliable Ca2+‐intercalation anode in tetraglyme (G4). When charged (reduced), graphite accommodates solvated Ca2+‐ions (Ca‐G4) and delivers a reversible capacity of 62 mAh g−1 that signifies the formation of a ternary intercalation compound, Ca‐G4·C72. Mass/volume changes during Ca‐G4 intercalation and the evolution of in operando X‐ray diffraction studies both suggest that Ca‐G4 intercalation results in the formation of an intermediate phase between stage‐III and stage‐II with a gallery height of 11.41 Å. Density functional theory calculations also reveal that the most stable conformation of Ca‐G4 has a planar structure with Ca2+ surrounded by G4, which eventually forms a double stack that aligns with graphene layers after intercalation. Despite large dimensional changes during charge/discharge (C/D), both rate performance and cyclic stability are excellent. Graphite retains a substantial capacity at high C/D rates (e.g., 47 mAh g−1 at 1.0 A g−1 s vs 62 mAh g−1 at 0.05 A g−1) and shows no capacity decay during as many as 2000 C/D cycles. As the first Ca2+‐shuttling calcium‐ion batteries with a graphite anode, a full‐cell is constructed by coupling with an organic cathode and its electrochemical performance is presented.
Details
- Language :
- English
- ISSN :
- 21983844 and 20190212
- Volume :
- 6
- Issue :
- 24
- Database :
- Directory of Open Access Journals
- Journal :
- Advanced Science
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.816acba6f4794d428b99d4a7bbdcd4a5
- Document Type :
- article
- Full Text :
- https://doi.org/10.1002/advs.201902129