Back to Search Start Over

Liquid Water Transport and Distribution in the Gas Diffusion Layer of a Proton Exchange Membrane Fuel Cell Considering Interfacial Cracks

Authors :
Bao Li
Shibo Cao
Yanzhou Qin
Xin Liu
Xiaomin Xu
Qianfan Xin
Source :
Energies, Vol 17, Iss 21, p 5339 (2024)
Publication Year :
2024
Publisher :
MDPI AG, 2024.

Abstract

The proton exchange membrane fuel cell (PEMFC), with a high energy conversion efficiency, has become an important means of hydrogen energy utilization. However, water condensation is unavoidable in the PEMFC because of low operating temperatures. The impact of liquid water on PEMFC performance and stability is significant. The gas diffusion layer (GDL) provides a critical transport path for liquid water in the PEMFC. Liquid water saturation and distribution in the GDL determine water flooding and mass transfer efficiency in the PEMFC. In this study, focusing on the effects of the water introduction method, osmotic pressure, and contact angle, the liquid water transport in the GDL was numerically investigated based on a pore-scale model using the volume of fluid (VOF) method. The results showed that compared with the conventional water introduction method without cracks, the saturation and spatial distribution of water inside the GDL obtained in the simulation were more consistent with the experimental results when the water was introduced through the microporous layer (MPL) crack. It was found that increasing the osmotic pressure resulted in a faster rate of water penetration, faster approaching the steady-state performance, and higher saturation. The ultra-high osmotic pressure contributed to the secondary breakthrough with a significant increase in saturation. Increasing the contact angle caused higher capillary resistance, especially in the region with small pore sizes. At a constant osmotic pressure, as the contact angle increased, the liquid water gradually failed to penetrate into the small pores around the transport path, causing saturation reduction and an ultimate failure to break through the GDL. Increasing the contact angle contributed to a higher breakthrough pressure and secondary breakthrough pressure.

Details

Language :
English
ISSN :
19961073
Volume :
17
Issue :
21
Database :
Directory of Open Access Journals
Journal :
Energies
Publication Type :
Academic Journal
Accession number :
edsdoj.839e20b1763549898bcac76ad5514bfa
Document Type :
article
Full Text :
https://doi.org/10.3390/en17215339