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Hidroformilação do oleato de metila catalisada por complexos de ródio
- Source :
- Química Nova, Vol 35, Iss 10, Pp 1940-1944 (2012)
- Publication Year :
- 2012
- Publisher :
- Sociedade Brasileira de Química, 2012.
-
Abstract
- In this work, we describe the hydroformylation of methyl oleate catalyzed by several rhodium complexes. Parameters including total pressure, phosphorous/rhodium and CO/H2 ratio, temperature and phosphorous ligands were scanned. Total conversion of the starting double bonds was achieved while maintaining excellent selectivity in aldehydes.
- Subjects :
- methyl oleate
hydroformylation
rhodium
Chemistry
QD1-999
Subjects
Details
- Language :
- English, Spanish; Castilian, Portuguese
- ISSN :
- 16787064 and 01004042
- Volume :
- 35
- Issue :
- 10
- Database :
- Directory of Open Access Journals
- Journal :
- Química Nova
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.84d91d404ff24c0c8a54d8083d04a534
- Document Type :
- article
- Full Text :
- https://doi.org/10.1590/S0100-40422012001000010