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Hidroformilação do oleato de metila catalisada por complexos de ródio

Authors :
Ana Nery Furlan Mendes
Ricardo Gomes da Rosa
José Ribeiro Gregório
Source :
Química Nova, Vol 35, Iss 10, Pp 1940-1944 (2012)
Publication Year :
2012
Publisher :
Sociedade Brasileira de Química, 2012.

Abstract

In this work, we describe the hydroformylation of methyl oleate catalyzed by several rhodium complexes. Parameters including total pressure, phosphorous/rhodium and CO/H2 ratio, temperature and phosphorous ligands were scanned. Total conversion of the starting double bonds was achieved while maintaining excellent selectivity in aldehydes.

Details

Language :
English, Spanish; Castilian, Portuguese
ISSN :
16787064 and 01004042
Volume :
35
Issue :
10
Database :
Directory of Open Access Journals
Journal :
Química Nova
Publication Type :
Academic Journal
Accession number :
edsdoj.84d91d404ff24c0c8a54d8083d04a534
Document Type :
article
Full Text :
https://doi.org/10.1590/S0100-40422012001000010