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Bis(2-{2-[2-(benzylcarbamoyl)phenoxy]acetamido}ethyl)ammonium nitrate ethanol disolvate

Authors :
Weisheng Liu
Guolin Zhang
Zhengdan Lu
Xiaoliang Tang
Jiaji Liu
Source :
Acta Crystallographica Section E, Vol 67, Iss 1, Pp o203-o204 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

In the title compound, C36H40N5O6+·NO3−·2C2H5OH, the nitrate anion is disordered over the two orientations of equal occupancy while the solvent molecule reveals large displacement parameters. The cation is formed by protonation of the N atom of a secondary amine in the middle of the flexible chain and the whole compound has crystallographically imposed C-2 symmetry with the crystallographic b axis. An O atom of the nitrate anion links the acidic H atoms of the cation via N—H...O hydrogen bonding. In addition, neighbouring cations are connected by intermolecular N—H...O hydrogen bonds and π–π interactions between the benzamide groups of the cations [centroid–centroid distance = 4.000 (3) Å], forming a chain along [001]. The ethanol solvent molecules are arranged on the side of the chain through O—H...O hydrogen bonds.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.85aebd96cb84db3a7650269c532871d
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810052670