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Bis(2-{2-[2-(benzylcarbamoyl)phenoxy]acetamido}ethyl)ammonium nitrate ethanol disolvate
- Source :
- Acta Crystallographica Section E, Vol 67, Iss 1, Pp o203-o204 (2011)
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography, 2011.
-
Abstract
- In the title compound, C36H40N5O6+·NO3−·2C2H5OH, the nitrate anion is disordered over the two orientations of equal occupancy while the solvent molecule reveals large displacement parameters. The cation is formed by protonation of the N atom of a secondary amine in the middle of the flexible chain and the whole compound has crystallographically imposed C-2 symmetry with the crystallographic b axis. An O atom of the nitrate anion links the acidic H atoms of the cation via N—H...O hydrogen bonding. In addition, neighbouring cations are connected by intermolecular N—H...O hydrogen bonds and π–π interactions between the benzamide groups of the cations [centroid–centroid distance = 4.000 (3) Å], forming a chain along [001]. The ethanol solvent molecules are arranged on the side of the chain through O—H...O hydrogen bonds.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.85aebd96cb84db3a7650269c532871d
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536810052670