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Ethyl (2E)-2-(2H-1,3-benzodioxol-5-ylmethylidene)-4-chloro-3-oxobutanoate

Authors :
Julio Zukerman-Schpector
Siti Nadiah Abd Salim
Paulo J. S. Moran
Bruno R. S. de Paula
J. Augusto R. Rodrigues
Edward R. T. Tiekink
Source :
Acta Crystallographica Section E, Vol 67, Iss 5, Pp o1044-o1044 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

In the title compound, C14H13ClO5, the five-membered ring is in an envelope conformation with the methylene C-atom being the flap. The conformation about the C=C double bond [1.341 (2) Å] is E. The chloropropan-2-one residue is approximately orthogonal to the remaining molecule [dihedral angle = 88.03 (6)°]. In the crystal, the molecules associate via C—H...O interactions, involving both carbonyl-O atoms, giving rise to an undulating two-dimensional array in the ac plane.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.8fea9f683dcf4804916d74231b96e494
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811011780