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1-(4-Bromophenyl)ferrocene

Authors :
Vincent O. Nyamori
Muhammad D. Bala
Source :
Acta Crystallographica Section E, Vol 64, Iss 11, Pp m1376-m1376 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

In the title compound, [Fe(C5H5)(C11H8Br)], the distance of the Fe atom from the centroids of the unsubstituted and substituted cyclopentadienyl (Cp) rings is 1.644 (1) and 1.643 (1) Å, respectively. The ferrocenyl moiety deviates from an eclipsed geometry, with marginally tilted Cp rings and an interplanar angle between the Cp and benzene rings of 13.0 (4)°. The crystal structure is stabilized by C—H...π interactions between a cyclopentadienyl H atom and the cyclopentadienyl ring of a neighbouring molecule.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
11
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.9501cf1eb9c142ac865de2178f50b3fe
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536808031759