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Charge-Transfer Adducts of Chalcogenourea Derivatives of N-Heterocyclic Carbenes with Iodine Monochloride
- Source :
- Molbank, Vol 2022, Iss 1, p M1344 (2022)
- Publication Year :
- 2022
- Publisher :
- MDPI AG, 2022.
-
Abstract
- In this communication, we investigate the reaction between seleno- and thiourea, derived from N-heterocyclic carbenes, with the interhalogen iodine monochloride. The formation of all three products was confirmed by NMR spectroscopy, while single-crystal X-ray analyses were able to establish a charge-transfer coordination type, which showed a linear Se/S-I-Cl arrangement, for all adducts formed. Based on a detailed crystallographic analysis, we can deduce the zwitterionic character of these compounds.
Details
- Language :
- English
- ISSN :
- 14228599 and 13985337
- Volume :
- 2022
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Molbank
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.9903b387ef494c1398533719b0a4e6a3
- Document Type :
- article
- Full Text :
- https://doi.org/10.3390/M1344