Back to Search
Start Over
Preparation and Structure Characterization of Iron(II)-Chelating Corn Oligopeptides
- Source :
- Shipin gongye ke-ji, Vol 44, Iss 4, Pp 243-251 (2023)
- Publication Year :
- 2023
- Publisher :
- The editorial department of Science and Technology of Food Industry, 2023.
-
Abstract
- Corn oligopeptides and ferrous chloride were used as raw materials to prepare iron (II)-chelating wheat oligopeptides. The chelating effect was evaluated by yield and chelating rate, and the best process was studied by single-factor, response surface centered design and verification experiments. The amino acid composition of iron(II)-chelating corn oligopeptides was determined by high performance liquid chromatography (HPLC), the structural characteristics of corn oligopeptides before and after chelating were analyzed by Fourier transform infrared radiation (FT-IR) and scanning electron microscope (SEM). The results showed that the optimum preparation conditions of iron (II)-chelating corn oligopeptides were as follows: Mass ratio between corn oligopeptides and ferrous chloride 5:1, pH7.0, chelating time 35 min, and chelating temperature 65 ℃. Under the conditions, the yield was 46.59%±1.69% and the iron (II) chelating rate was 51.75%±2.10%. The content of essential amino acids in iron(II)-chelating corn oligopeptides accounted for 25.58%, and the components with relative molecular weight less than 1000 u accounted for as high as 89.77%. FTIR analysis results showed that iron (II) formed coordination bonds with nitrogen and oxygen atoms in the terminal carboxyl or amino group of the corn oligopeptides to form iron (II)-chelating corn oligopeptides. SEM results showed that after chelating the molecules aggregated and the spherical structure disappeared, indicating that a new type of iron(II)-chelating corn oligopeptides was successfully formed.
Details
- Language :
- Chinese
- ISSN :
- 10020306
- Volume :
- 44
- Issue :
- 4
- Database :
- Directory of Open Access Journals
- Journal :
- Shipin gongye ke-ji
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.9eb4fe9847904684b62dc893d463f9cf
- Document Type :
- article
- Full Text :
- https://doi.org/10.13386/j.issn1002-0306.2022050157