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Poly[μ2-aqua-μ4-(2-{3-[(6-chloropyridin-3-yl)methyl]-2-oxoimidazolidin-1-yl}acetato)-sodium]

Authors :
Rajni Kant
Vivek K. Gupta
Kamini Kapoor
Chetan S. Shripanavar
Kaushik Banerjee
Madhukar B. Deshmukh
Source :
Acta Crystallographica Section E, Vol 68, Iss 7, Pp m891-m892 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

In the title compound, [Na(C11H11ClN3O3)(H2O)]n, there are two independent NaI ions, one of which lies on an inversion center and is coordinated in a slightly distorted octahedral environment. The other NaI ion lies on a twofold rotation axis and is cooordinated in a slightly distorted trigonal–bipyramidal coordination environment. In the organic ligand, the imidazolidine ring adopts a half-chair conformation. The NaI ions bridge organic ligands and water molecules, forming a two-dimensional structure parallel to (100). There are intermolecular O—H...O and weak C—H...O hydrogen bonds within the two-dimensional structure.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b1bc987005b4d4c932c7d5917c09c0a
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812025007