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Di-μ-adipato-κ4O1,O1′:O6,O6′-bis[(2,2′-dipyridylamine-κ2N,N′)zinc(II)] trihydrate
- Source :
- IUCrData, Vol 9, Iss 9, p x240906 (2024)
- Publication Year :
- 2024
- Publisher :
- International Union of Crystallography, 2024.
-
Abstract
- The title compound, [Zn2(C6H8O4)2(C10H9N3)2]·3H2O or {Zn2[(C5H4N)2NH]2[μ-(CH2)4(COO)2]2}·3H2O, was separated from the solvothermal reaction of zinc(II) sulfate heptahydrate, 2,2′-dipyridylamine and sodium adipate. The dinuclear metal complex has a centrosymmetric structure, with the ZnII atom adopting a highly distorted octahedral coordination sphere composed of four oxygen atoms from bridging adipato ligands and two pyridine nitrogen atoms. In the crystal, the title compound aggregates into a tri-periodic supramolecular structure through intermolecular hydrogen-bonding networks of the form O—H...O and N—H...O.
Details
- Language :
- English
- ISSN :
- 24143146
- Volume :
- 9
- Issue :
- 9
- Database :
- Directory of Open Access Journals
- Journal :
- IUCrData
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.b6c0bb1d92431982779e63ca05ee65
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2414314624009064