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{μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III)

Authors :
Peng Chen
Guang-Ming Li
Peng-Fei Yan
Fan Yang
Yan Bao
Source :
Acta Crystallographica Section E, Vol 66, Iss 12, Pp m1683-m1684 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the title dinuclear CuII–LuIII salen-type complex, [CuLu(C22H24N2O4)(NO3)3], with the ligand 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolate, the irregular nine-coordinate LuIII coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu—O = 2.230 (3)–2.621 (4) Å]. The slightly distorted square-planar four-coordinate CuII atom comprises two imine N atoms [Cu—N = 1.903 (4) and 1.912 (4) Å] and two phenolate O atoms from the ligand molecule [Cu—O = 1.897 (3) and 1.906 (3) Å]. All atoms of the cyclohexane ring of the ligand molecule are disordered over two sets of sites with equal occupancy.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.f50936d5503f4427820c9c81158ef0e7
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810048245