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{μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III)
- Source :
- Acta Crystallographica Section E, Vol 66, Iss 12, Pp m1683-m1684 (2010)
- Publication Year :
- 2010
- Publisher :
- International Union of Crystallography, 2010.
-
Abstract
- In the title dinuclear CuII–LuIII salen-type complex, [CuLu(C22H24N2O4)(NO3)3], with the ligand 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolate, the irregular nine-coordinate LuIII coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu—O = 2.230 (3)–2.621 (4) Å]. The slightly distorted square-planar four-coordinate CuII atom comprises two imine N atoms [Cu—N = 1.903 (4) and 1.912 (4) Å] and two phenolate O atoms from the ligand molecule [Cu—O = 1.897 (3) and 1.906 (3) Å]. All atoms of the cyclohexane ring of the ligand molecule are disordered over two sets of sites with equal occupancy.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 66
- Issue :
- 12
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.f50936d5503f4427820c9c81158ef0e7
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536810048245