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Crystal structure and Hirshfeld surface analysis of dimethyl 2-oxo-4-(pyridin-2-yl)-6-(thiophen-2-yl)cyclohex-3-ene-1,3-dicarboxylate

Authors :
Farid N. Naghiyev
Victor N. Khrustalev
Mehmet Akkurt
Elnur Z. Huseynov
Ajaya Bhattarai
Ali N. Khalilov
İbrahim G. Mamedov
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 6, Pp 654-658 (2024)
Publication Year :
2024
Publisher :
International Union of Crystallography, 2024.

Abstract

In the title compound, C19H17NO5S, the cyclohexene ring adopts nearly an envelope conformation. In the crystal, molecules are linked by C—H...O hydrogen bonds, forming a three-dimensional network. In addition, C—H...π interactions connect the molecules by forming layers parallel to the (010) plane. According to the Hirshfeld surface analysis, H...H (36.9%), O...H/H...O (31.0%), C...H/H...C (18.9%) and S...H/H...S (7.9%) interactions are the most significant contributors to the crystal packing.

Details

Language :
English
ISSN :
20569890
Volume :
80
Issue :
6
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.f5419defa2f44a6daf464df537785dfb
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989024004687