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Coherent structural trapping through wave packet dispersion during photoinduced spin state switching
- Source :
- Nature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
- Publication Year :
- 2017
- Publisher :
- Nature Portfolio, 2017.
-
Abstract
- Ultrafast nonadiabatic chemical dynamics during molecular photo-transformations remain challenging to describe since electronic/nuclear configurations are coupled. Here the authors use time-resolved X-ray absorption spectroscopy to probe the light-induced spin-state trapping dynamics of [Fe(bpy)3]2+beyond the Born-Oppenheimer approximation.
- Subjects :
- Science
Subjects
Details
- Language :
- English
- ISSN :
- 20411723
- Volume :
- 8
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Nature Communications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.f550e3664db64b8489fa20caa1ce88e4
- Document Type :
- article
- Full Text :
- https://doi.org/10.1038/ncomms15342