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Zirconoarylation of alkynes through p-chloranil-promoted reductive elimination of arylzirconates
- Source :
- Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 528-534 (2014)
- Publication Year :
- 2014
- Publisher :
- Beilstein-Institut, 2014.
-
Abstract
- A novel method for the zirconoarylation of alkynes was developed. TCQ-promoted reductive elimination of arylzirconate [LiCp2ZrAr(RC≡CR)], which was prepared by the reaction of zirconocene–alkyne complexes with aryllithium compounds, afforded trisubstituted alkenylzirconocenes. This reaction can afford multi-substituted olefins with high stereoselectivity.
Details
- Language :
- English
- ISSN :
- 18605397
- Volume :
- 10
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Beilstein Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.f72b5d74c249ca8d9945dde52f4229
- Document Type :
- article
- Full Text :
- https://doi.org/10.3762/bjoc.10.48