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Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate

Authors :
Jian-Ping Zhao
Rui-Qin Liu
Zhi-Hao Jiang
Sheng-Di Bai
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 1, Pp o28-o29 (2015)
Publication Year :
2015
Publisher :
International Union of Crystallography, 2015.

Abstract

The asymmetric unit of the title compound, C15H16N2·C4H8O, contains two amidine molecules (A and B) with slightly different conformations and two tetrahydrofuran (THF) solvent molecules. In the amidine molecules, the dimethylphenyl ring and the NH2 group lie to the same side of the N=C bond and the dihedral angles between the aromatic rings are 54.25 (7) (molecule A) and 58.88 (6) ° (molecule B). In the crystal, N—H...N hydrogen bonds link the amidine molecules into [100] C(4) chains of alternating A and B molecules. Both amidine molecules form an N—H...O hydrogen bond to an adjacent THF solvent molecule.

Details

Language :
English
ISSN :
20569890
Volume :
71
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.fae4e5004f968effa0327999a5ac
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989014026255