Metal–Site Dispersed Zinc–Chromium Oxide Derived from Chromate–Intercalated Layered Hydroxide for Highly Selective Propane Dehydrogenation

Propane dehydrogenation (PDH) is a crucial approach for propylene production. However, commonly used CrOx–based catalysts have issues including easy sintering at elevated reaction temperatures and relying on high acidity supports. In this work, we develop a strategy, to strongly anchor and isolate active sites against their commonly observed aggregation during reactions, by taking advantage of the net trap effect in chromate intercalated Zn–Cr layered hydroxides as precursors. Furthermore, the intercalated chromate overcomes the collapse of traditional layered hydroxides during their transformation to metal oxide, thus exposing more available active sites. A joint fine modulation including crystal structure, surface acidity, specific surface area, and active sites dispersion is performed on the final mixed metal oxides for propane dehydrogenation. As a result, Zn1Cr2–CrO42−–MMO delivers attractive propane conversion (~27%) and propylene selectivity (>90%) as compared to other non–noble–metal–based catalysts.