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Dynamics in the Mn(sup)2+ binding site in single crystals of concanavalin A revealed by high-field EPR spectroscopy

Authors :
Carmieli, Raanan
Manikandan, Palanichamy
Epel, Boris
Kalb (Gilboa), A. Joseph
Schnegg, Alexander
Savitsky, Anton
Mobius, Klaus
Goldfarb, Daniella
Source :
Biochemistry. July 1, 2003, Vol. 42 Issue 25, 7863-7870
Publication Year :
2003

Abstract

Results reveal two types of manganese with zero-field splitting tensors at low temperatures in single crystals of concanavalin A. At room temperature, the crystals display one type of manganese. Temperature dependent electron paramagnetic resonance spectra suggest a two-state conformational equilibria at 200K absolute temperature.

Details

Language :
English
ISSN :
00062960
Volume :
42
Issue :
25
Database :
Gale General OneFile
Journal :
Biochemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.105737333