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Diastereoselective 14 beta-hydroxylation of baccatin III derivatives

Authors :
Baldelli, Eleonora
Bataglia, Arturo
Bombardelli, Ezio
Carenzi, Giacomo
Fontana, Gabriele
Gambini, Andrea
Gelmi, Maria Luisa
Guerrini, Andrea
Pocar, Donato
Source :
Journal of Organic Chemistry. Dec 12, 2003, Vol. 68 Issue 25, 9773-9779
Publication Year :
2003

Abstract

The 14-beta hydroxybaccatin III is the starting material for the synthesis of the second-generation anticancer taxoid ortataxel. The 10-deacetylbaccatin III is used to synthesize the 7-tert-butoxycarbonyl, and 7-triethylsilyl derivatives of 14-beta hydroxybaccatin III 1, 14-carbonate.

Details

Language :
English
ISSN :
00223263
Volume :
68
Issue :
25
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.119174135