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Synthesis, structure, and dynamics of nickelacarboranes incorporating the [nido-7,9-C2B9H11](super 2-) ligand

Authors :
Hodson, Bruce E.
McGrath, Thomas D.
Stone, F. Gordon A.
Source :
Inorganic Chemistry. May 17, 2004, Vol. 43 Issue 10, 3090-3097
Publication Year :
2004

Abstract

It been shown that compounds of the forms [2,2-L2-closo-2,1,7-NiC2B9H11], which display interesting dynamic properties in solution is obtained by protonation of the species [NEt4]-[2-(eta3-C3H4R)-closo-2,1,7-NiC2B9H11] (R = H, Ph) in the presence of donors (L = CO, CNBut, L2 = diene).

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
10
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.119353779