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Luminescent Ag(super 1)-Cu(super 1) heterometallic hexa-, octa-, and hexadecanuclear alkynyl complexes
- Source :
- Inorganic Chemistry. May 31, 2004, Vol. 43 Issue 11, 3484-3491
- Publication Year :
- 2004
-
Abstract
- Self-assembly incorporation of metal components(AgC triple bond CC6H4R-4)(sub n) and [Cu(mu-Ph2PXPh2)(sub 2)(MeCN)(sub 2)]-(CIO4)2(X=NH,CH2) gave bicapped cubic Ag(super 1)Cu(super 1)(sub 2) complexes for X=NH, whereas waterwheel-like Ag(super 1)(sub 6)Cu(super 1)(sub 2) or Ag(super 1)(sub 12)Cu(super 1)(sub 4) complexes were afforded when X=CH2. The complexes emit intense luminescence.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 43
- Issue :
- 11
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.122903557