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Is the allylpalladium structure altered between solid and solutions?
- Source :
- Journal of the American Chemical Society. July 28, 2004, Vol. 126 Issue 29, p9079, 6 p.
- Publication Year :
- 2004
-
Abstract
- The EXAFS measurements have been interpreted as the cation (dppe)Pd[H2-CC(H)CMe(sub 2)](super +) has different structures in the solid phase and in THF solution. This structural alteration was suggested to play a role in governing the regioselectivity of the nucleophilic addition to the allyl carbons.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 126
- Issue :
- 29
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.123113107