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Is the allylpalladium structure altered between solid and solutions?

Authors :
Clot, Eric
Eisenstein, Odile
Weng, Tsu-Chien
Penner-Hahn, James
Caulton, Kenneth J.
Source :
Journal of the American Chemical Society. July 28, 2004, Vol. 126 Issue 29, p9079, 6 p.
Publication Year :
2004

Abstract

The EXAFS measurements have been interpreted as the cation (dppe)Pd[H2-CC(H)CMe(sub 2)](super +) has different structures in the solid phase and in THF solution. This structural alteration was suggested to play a role in governing the regioselectivity of the nucleophilic addition to the allyl carbons.

Details

Language :
English
ISSN :
00027863
Volume :
126
Issue :
29
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.123113107