Infrared multiphoton Si isotope selective dissociation of phenyltrifluorosilane under free electron laser irradiation

Authors :: Chernyshev, Andrei V.
Nomaru, Keiji
Petrov, Alexander K.
Chesnokov, Evgeni N.
Gorelik, Sergey R.
Kuibida, Leonid V.
Akberdin, Rustan R.
Kuroda, Haruo
Source :: Journal of Physical Chemistry A. Nov 6, 2003, Vol. 107 Issue 44, 9362-9367
Publication Year :: 2003
Abstract: Infrared Free electron laser (FEL) is used that induced isotopically selective multiphoton dissociation of PhSiF3 molecules in the gaseous phase. The longer and broader FEL pulse is partially responsible for the lower selectivity. FEL experiments with PhSiF3 performed in a batch mode may also be responsible for the lower selectivity.

Subjects :: Molecules -- Research
Fluorine -- Research
Silicon compounds -- Research
Chemicals, plastics and rubber industries

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