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Modifying electronic communication in dimolybdenum units by linkage isomers of bridged oxamidate dianions

Authors :
Cotton, F. Albert
Chun Y. Liu
Murillo, Carlos A.
Villagran, Dino
Wang, Xiaoping
Source :
Journal of the American Chemical Society. Nov 5, 2003, Vol. 125 Issue 44, p13564, 12 p.
Publication Year :
2003

Abstract

Linkage isomers bridged oxamidate dianions are used for modifying electronic communication in dimolybdenum units. The results suggest that the pi interaction over the entire fused bicyclic chelating ring could be responsible for the metal-metal interaction and also indicates the presence of a strong electronic communication between the two linked dimetal units.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
44
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.123427802