Temperature dependence of (SCN)(sub 2)(super dot-) in water at 25-400 degree Celsius: absorption spectrum, equilibrium constant, and decay

The temperature dependence of the absorption spectrum of the formation and decay of dimer anion (SCN)(sub 2)(super dot-) is analysed in the temperature range of 25 to 400 degree Celsius. Analysis showed that the absorption peak shift to longer wavelength (red shift) with increase in temperature.