An unusual equilibrium chlorine atom transfer process and its potential for assessment of steric pressure by bulky aryls

Authors :: Smith, Rhett C.
Shah, Shashin
Urnezius, Eugenijus
Pretasiewicz, John D.
Source :: Journal of the American Chemical Society. Jan 8, 2003, Vol. 125 Issue 1, p40, 2 p.
Publication Year :: 2003
Abstract: The synthesis and characterization of stable phosphanylidene-sigma(super 4)-phosphoranes such as Mes*P = PMe3 and 2,6-Mes2C6H3P = PMe3 is reported. Studies indicate potential catalytic role of phosphine in chlorine atom transfer processes.

Subjects :: Chlorine -- Atomic properties
Aromatic compounds -- Atomic properties
Chemistry

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