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Anomalous intramolecular C-H insertion reactions of rhodium carbenoids: factors influencing the reaction course and mechanistic implications
- Source :
- Journal of Organic Chemistry. May 28, 2004, Vol. 69 Issue 11, p3886, 13 p.
- Publication Year :
- 2004
-
Abstract
- Rhodium carbenoids were inserted into the alpha-C-H bonds of allylic ethers to produce 3(2H)-furanones. In addition to the expected 3(2H)-furanones, unexpected acetal products from an anomalous C-H insertion process were obtained.
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 69
- Issue :
- 11
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.123677672