Spectroscopic investigations of Bis(sulfoximine) copper(II) complexes and their relevance in asymmetric catalysis

Authors :: Bolm, Carsten
Martin, Marc
Gescheidt, Georg
Palivan, Cornelia
Neshchadin, Dmytro
Harmer, Jeffrey
Mitrikas, George
Schweiger, Arthur
Feth, Martin
Bertagnolli, Helmut
Source :: Journal of the American Chemical Society. May 21, 2003, Vol. 125 Issue 20, p6222, 6 p.
Publication Year :: 2003
Abstract: The structure of Copper(II) complex formed within the course of a stereoselective Diels-Alder reaction was investigated by EXAFS, CW-EPR at X- and W-band, HYSCORE, pulsed ENDOR, and UV-vis spectroscopy. The experimental techniques indicate that the chiral bis(sulfoximine) ligand (S,S)-1 and the dienophile forma tetragonally distorted complex in CH2Cl2.

Subjects :: Diels-Alder reaction -- Analysis
Copper -- Structure
Copper -- Chemical properties
Spectrum analysis -- Usage
Chemistry

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