Structural chemistry of 'Defect' cyanometalate boxes: {Cs subset [CpCo(CN)3] (sub 4) [CpRu] (sub 3)} and {M subset [CpRh(CN)3] (sub 4) [Cp*Ru] (sub 3)} (M = NH4, Cs)

Authors :: Kuhlman, Matthew L.
Rauchfuss, Thomas B.
Source :: Journal of the American Chemical Society. August 20, 2003, Vol. 125 Issue 33, p10084, 9 p.
Publication Year :: 2003
Abstract: The structural chemistry of cation-containing defect cyanometalate boxes is elucidated. A promising motif for cation receptors is represented by the defect box as these cations are more solvent-accessible and kinetically labile.

Subjects :: Carbon compounds -- Chemical properties
Ruthenium -- Chemical properties
Cations -- Chemical properties
Chemistry

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