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A planar tetracoordinate carbon and unusual bonding in an Organodimetallic Propynylidene complex arising from double-C-H activation of an alene ligand
- Source :
- Journal of the American Chemical Society. Feb 19, 2003, Vol. 125 Issue 7, p1688, 2 p.
- Publication Year :
- 2003
-
Abstract
- Propynylidene 1 (HCCCH) is the simplest alkynylcarbene that, along with abundant interstellar cyclopropenylidene 2 and propadienylidene 3 has attracted substantial interest. The propynylidene can be generated as an organodimetallic ligand in solution by double C-H activation of allene and it can adopt a curved structure.
- Subjects :
- Carbon -- Chemical properties
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 125
- Issue :
- 7
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.123818637